Product ID:VERSI-FOAM SYS 15,50 & REFILLABLE CLASS I & MSDA COMPONENT A
MSDS Date:06/15/1996
FSC:9330
NIIN:00N078295
Status Code:A
Kit Part:Y
MSDS Number: CJPYM

RHH FOAM SYSTEMS INC

6001 SOUTH PENNSYLVANIA AVE
CUDAHY, WI 53110-0752
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 800-657-0702

Preparer: DEBRA M. BUSS

Cage: RHHFO

RHH FOAM SYSTEMS INC

752 CUDAHY, WI 53110-0752 US

Telephone: 800-657-0702

Cage: RHHFO

4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI)

CAS: 101-68-8

RTECS: NQ9350000

OSHA PEL C0.2 MG/M3;C0.02 PPM

ACGIH TLV: 0.051 MG/M3;.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

POLYMERIC MDI

CAS: 9016-87-9

RTECS: TR0350000

OSHA PEL N/K

ACGIH TLV: N/K

CHLORODIFLUOROMETHANE

CAS: 75-45-6

RTECS: PA6390000

OSHA PEL N/K

ACGIH TLV: 3540 MG/M3;1000 PPM

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUTION! CONTENTS UNDER PRESSURE.
IRRITATING TO EYES, SKIN AND RESPIRATORY TRACT. MAY CAUSE
SENSITIZATION BY SKIN CONTACT AND INHALATION. SYMPTOMS MAY INCLUDE
COUGHING, WHEEZING AND SHORTNESS OF BREAT H. CHLOROFLUOROCARBON
MATERIALS HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO
EPINEPHRINE IN LABORATORY ANIMALS AND COULD HAVE A SIMILAR EFFECT
IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY
OR CHRONICALLY EXPOSED TO CHLOROFLUOROCARBONS .
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:EXPOSURE TO INDIVIDUALS WITH
ASTHMA, ECZEMA AND/OR ALLERGIES MAY AGGRAVATE EXISTING CONDITIONS.

First Aid:IN ALL CASES, SEEK ADDITIONAL MEDICAL ATTENTION. EYES: FLUSH
WITH CLEAN, LOW PRESSURE WATER FOR AT LEAST 15 MINUTES, WHILE
HOLDING EYELIDS OPEN. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN
WITH SOAP AND WATER. INHALATION: REMOVE FROM CONTAMINATED AREA TO
FRESH AIR. INGESTION: IN CASE OF EXCESSIVE INGESTION, GIVE LARGE
AMOUNTS OF LIQUIDS. DO NOT INDUCE VOMITING.

Flash Point:>198.9C, 390.F
ESTIMATED
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA AND
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DURING COMBUSTION, CARBON MONOXIDE AND
CARBON DIOXIDE, NITROGEN OXIDES, AMMONIA AND TRACE AMOUNTS OF
HYDROGEN CYANIDE ARE GIVEN OFF. THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE .

Spill Release Procedures:PROVIDE ADEQUATE VENT. WEAR SUITABLE PERSONAL
PROTECTIVE CLOTHING & EQUIPMENT. CONTAIN SPILL & COLLECT USING
SUITABLE ABSORBENT MATERIAL SUCH AS SAWDUST/VERMICULITE. SHOVEL
INTO WASTE CONTAINER ADDING DECONTAMINATE SOLUTION (90% WATER, 7%
AMMONIA & 3% LIQUID DETERGENT). LEAVE UNCOVERED FOR 24 HOURS PRIOR
TO DISPOSAL. DISPOSAL OF AS ORDINARY INDUSTRIAL WASTE IN COMPLIANCE
W/PERTINENT REGULATIONS.

Handling and Storage Precautions:PROVIDE ADEQUATE VENTILATION. WEAR
SUITABLE PERSONAL PROTECTIVE CLOTHING AND EQUIPMENT. CAUTION!
CONTENTS UNDER PRESSURE.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:USE ONLY IN WELL-VENTILATED AREAS. WITH
INSUFFICIENT VENTILATION, OR WHERE POTENTIAL EXISTS FOR EXCEEDING
THE TLV, WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS.
Protective Gloves:WEAR CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR PROTECTIVE CLOTHING.
Supplemental Safety and Health
PHYSICAL/CHEMICAL PROPERTIES: VOC CONTENT: 0 LBS/GAL.

Vapor Pres:2700 MMHG @ 70F/21C
Spec Gravity:1.3
Appearance and Odor:DARK BROWN FROTHY LIQUID, WITH A MILD ODOR.

Stability Indicator/Materials to Avoid:YES
REACTS WITH WATER. AVOID ALKALIES, ACIDS, ALCOHOL AND AMMONIA. REACTION
MAY BE VIOLENT AT ELEVATED TEMPERATURES.
Stability Condition to Avoid:AVOID OPEN FLAMES, STORAGE TEMPERATURES
ABOVE 120F (49C). DO NOT INCINERATE CYLINDERS.
Hazardous Decomposition Products:HCL, PHOSGENE .

Waste Disposal Methods:PRIOR TO DISPOSAL, CYLINDERS MUST BE PROPERLY
VENTED. DO NOT PUNCTURE OR INCINERATE CYLINDERS. DISPOSE OF AS
ORDINARY INDUSTRIAL WASTE IN COMPLIANCE WITH PERTINENT REGULATIONS.
DISPOSE OF IN ACCORDANC E WITH LOCAL, STATE, AND FEDERAL
REGULATIONS .

Toxicological Information:CONCENTRATION OF COMPONENTS (INGREDIENTS
SECTION) MUST BE CONSIDERED TO DETERMINE THE EFFECTS OF THIS
MIXTURE. MDI: LD50: 15 GM/KG (RAT, INGESTION).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:4,4-DIPHENYLMETHANE-DIISOCYANATE (MDI): SARA
311/312/313. CHLORODIFLUOROMETHANE: SARA 311/312/313.
Federal Regulatory Information:4,4-DIPHENYLMETHANE-DIISOCYANATE (MDI):
CAA 1990 TOXIC AIR POLLUTANT. CHLORODIFLUOROMETHANE: CANADA.
State Regulatory Information:CHLORODIFLUOROMETHANE: MA, NJ, PA.